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00Technical resources

Technical resources: PVC additive selection, specifications and handling guides

Short, practical references written for procurement teams and technical buyers: how to read a specification, how to shortlist a stabilizer, how plasticizers and chlorinated paraffin grades differ, and how to store what you buy.

01Guide

How to read a calcium carbonate specification for PVC

Five numbers on a CaCO₃ data sheet explain most of how it will behave in a PVC compound.

D50 (median particle size)
Sets the average surface area available for wetting and affects stiffness and opacity. Finer D50 generally increases the demand for lubricant and coating quality.
D97 (coarse tail)
Indicates the coarse fraction. A high D97 can show up as surface defects or reduced impact strength, especially in thin sections and profiles. Compare D97, not just D50, between suppliers.
Oil absorption
Higher absorption means the filler takes up more plasticizer or lubricant, which influences how much the formulation must be rebalanced. Our Super-series grades list 23 g / 100 g.
Whiteness and brightness
Matter for colour and for how much titanium dioxide or pigment is required. The method and instrument should be stated, as here (Minolta, Japan).
Coating (stearic acid %) and coverage
On a coated grade, ask both for the stearic acid level and the percentage of surface coated. Our Super-C series lists 1.20 % and 100 %.
Moisture and acid insoluble
Moisture drives voids and surface defects in extrusion. Acid-insoluble content indicates mineral impurities such as silica.

02Guide

Selecting a PVC heat stabilizer: a short decision guide

Start from the product and the market, then narrow by chemistry. This table is a starting point for trials, not a recommendation.

Selecting a PVC heat stabilizer: a short decision guide
If your product is…Shortlist to evaluateQuestions to settle first
Rigid pipe, fittings, conduitLead-based one-pack; Ca/Zn one-pack; COPS for CPVCDestination market rules on lead; potable-water standards; filler loading
Window / technical profile, siding, panelsCa/Zn one-pack; tin; lead-basedWeathering and colour stability; surface finish
Foam board / CelukaCa/Zn or lead-based with foam-compatible lubricantsFoaming agent and lubricant balance
Cable insulation and sheathingLead-based or Ca/Zn with suitable plasticizer systemElectrical and thermal-ageing requirements; plasticizer type
Flexible film, sheet, leather cloth, flooringLiquid Ba/Zn or Ca/Zn with ESBOOdour, plate-out, transparency

Always confirm suitability with a trial in your own formulation and process.

03Guide

Primary and secondary plasticizers, and reading a chlorinated paraffin grade code

A primary plasticizer does the plasticizing; a secondary plasticizer extends it. Both matter to cost and to the properties you need.

Primary plasticizers
DOP, odourless DOP and DBP are compatible with PVC at high ratios and set the basic flexibility of the compound.
Secondary plasticizers
Chlorinated paraffin is blended with a primary plasticizer to adjust cost, flame performance and other properties. It is used at lower ratios.
Chlorinated paraffin grade code
Letter = series (A or B). Digit = chlorine level: 1 ≈ 62 %, 2 ≈ 52 %, 3 ≈ 42 % w/w. B series is more viscous and less volatile than A at the same chlorine level.
Compare on process, not only on name
Volatile loss at 180 °C and thermal stability index tell you how a grade will behave under processing heat.

04Guide

Storage and handling quick reference

General good-practice guidance. The safety data sheet for your product always takes precedence.

Storage and handling quick reference
MaterialStorageHandling note
Calcium carbonate (powder)Cool, dry, covered, on palletsReseal opened bags; fine powder absorbs moisture and cakes
Plasticizers (DOP, DBP, ODOP)Closed, clean, dry containers; away from heat and oxidisersDedicated transfer equipment; avoid moisture and contamination
Chlorinated paraffinClosed containers; away from heat and ignition sourcesGentle warming eases flow of viscous grades; follow the SDS
Lead-based stabilizersLabelled closed containers, access-controlled, dryAvoid dust; wash facilities; no eating, drinking or smoking in the area
Ca/Zn and stearates (powder)Cool, dry, closed bagsLimit dust; first-in first-out rotation
Liquid stabilizers, ESBOClosed containers away from heatMix gently before use if the product separates; follow the SDS

05Guide

Procurement checklist: what to ask any additives supplier

These are the questions we would want answered if we were buying. Use them with us and with anyone else.

  1. Is the supplier the manufacturer, an importer or a distributor, and who is the manufacturer of this grade?
  2. What is the country of origin, and can origin be stated on the documentation?
  3. Which documents are available: technical data sheet, certificate of analysis, safety data sheet?
  4. Are the specification values typical, or guaranteed limits per lot?
  5. Which test methods are referenced, and are they listed next to each value?
  6. Pack type, pack size, net weight, labelling and minimum order quantity.
  7. Lead time, stock position and how urgent orders are handled.
  8. Regulatory position of the grade in your destination market.
  9. Whether a pre-shipment sample can be supplied for approval.

07Reference

Glossary

COA
Certificate of analysis: lot-specific test results issued with a shipment.
COPS
Complete one-pack system: stabilizer and lubricant combined in one product.
CP
Chlorinated paraffin.
D50 / D97
Median particle size / size below which 97 % of particles fall.
DOP / DBP
Di-octyl phthalate / di-n-butyl phthalate plasticizers.
ESBO
Epoxidised soya bean oil.
Hazen unit
Platinum-cobalt colour scale used for near-colourless liquids.
K.F.
Karl Fischer titration for moisture.
One-pack
A pre-blended additive package dosed as a single product.
SDS
Safety data sheet.
TDS
Technical data sheet.

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